Explosive volcanism is one of the most catastrophic material failure phenomena. During magma ascent, fragmentation produces particulate magma, which, if deposited above the glass transition of the interstitial melt, will sinter viscously. In-conduit tuffisites, conduit wall breccias and ash deposited from exceptionally hot pyroclastic flows are scenarios in which sintering by viscous flow is possible. Therefore, understanding the kinetics of sintering and the characteristic timescales over which magma densifies are critical to understanding the degassing timeframe in conduits and deposits. Viscous sintering is accompanied by a recovery of material strength towards that of a pore-free, dense magma. Understanding damage mechanisms and seismic behaviour prior to failure of sintered volcanic products are also crucial for the application of micromechanical models and material failure forecasting laws. Powdered standard glass and industrial glass beads have been used to explore sintering mechanisms at ambient pressure conditions and temporal evolution of connected and isolated pore-structure. I observe that sintering under low axial stress is essentially particle size, surface tension and melt viscosity controlled. I found that the timescales over which the bulk density approaches that of a pore-free melt at a given temperature is dependent on the particle-contact surface area, which can be estimated from the particle shape, the packing type and the initial total porosity. Granulometric constraint on the starting material indicates that the fraction of finer particles controls the rate of sintering as they cluster in pore spaces between larger particles and have a higher driving force for sintering due to their higher surface energy to volume ratio. Consequently, the resultant sample suite has a range of microstructures because the viscous sintering process promotes a fining of pores and a coarsening of particles. In a volcano, newly formed sintering material will then further contribute to magma-plugging of the conduit and its mechanical properties will affect magma rupture and its associated precursory signals. This consideration permitted me to explore the effect of sintering on the stress required for dynamic macroscopic failure of synthesised samples and assess the ability of precursory microseismic signals to be used as a failure forecast proxy at conditions relevant to shallow volcanic conduits. To this end, the samples were subjected to mechanical tests under a constant rate of deformation and at a temperature in the region of the material glass transition. A dual acoustic emission rig was employed to track the occurrence of brittle fracturing. The monitored acoustic dataset was then exploited to systematically assess the accuracy of the failure forecasting method as a function of heterogeneity (cast as porosity) since it acts as nucleating site for fracture propagation. The pore-emanating crack model describes well the peak stress at failure in the elastic regime for these materials. I show that the failure forecast method predicts failure within 0-15% error at porosities >0.2. However, when porosities are <0.2, the forecast error associated with predicting the failure time increases to >100%. I interpret these results as a function of the low efficiency with which strain energy can be released in the scenario where there are few or no heterogeneities from which cracks can propagate. These observations shed light on questions surrounding the variable efficacy of the failure forecast method applied to active volcanoes. In particular, they provide a systematic demonstration of the fact that a good understanding of material properties is required. Thus I wish to emphasise the need for a better coupling of empirical failure forecasting models with mechanical parameters, such as failure criteria for heterogeneous materials, and point to the implications of this for a broad range of material-based disciplines.